N-Ethylbenzylammonium Fluorochromate (VI) Adsorbed on Silica Gel, a Mild and Selective Heterogeneous Reagent
A mild and selective method for the oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones with N-ethylbenzylammonium fluorochromate (VI), EBAFC, is reported. Stability, reaction rate, ease of work-up and efficiency of the EBAFC are considerably increased upon its adsorption on silica gel. The N-emylbenzylammonium fluorochromate (VI) adsorbed on silica gel is inert to aldehydes, ketones, oximes, thiols, sulfides, phenols, pyrans, trimethylsilanes, malonates and thioacetamides.
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| Main Authors: | , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Química de México A.C.
2010
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| Online Access: | http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2010000400008 |
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| Summary: | A mild and selective method for the oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones with N-ethylbenzylammonium fluorochromate (VI), EBAFC, is reported. Stability, reaction rate, ease of work-up and efficiency of the EBAFC are considerably increased upon its adsorption on silica gel. The N-emylbenzylammonium fluorochromate (VI) adsorbed on silica gel is inert to aldehydes, ketones, oximes, thiols, sulfides, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. |
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