METHOXYCARBONYLATION OF STYRENE BY PALLADIUM(II) COMPLEX CONTAINING THE DIPHENYLPHOSPHINOCYRHETRENE LIGAND
The palladium-catalyzed methoxycarbonylation of vinylarenes has been investigated for the first time using phosphinocyrhetrene [(Ti5-C5H4PPh2)Re(CO)3] a non-metallocenic organometallic ligand. The catalytic system trans-[(T5-C5H4PPh2)Re(CO)3]PdCl2(NCMe)/PPh3 (1:2 ratio), carbon monoxide and methanol, in the presence of HCl as acidic promoter, showed good catalytic activity, excellent regioselectivity to the branched products and chemoselectivity up to 94%.
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| Main Authors: | , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2012
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000200009 |
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| Summary: | The palladium-catalyzed methoxycarbonylation of vinylarenes has been investigated for the first time using phosphinocyrhetrene [(Ti5-C5H4PPh2)Re(CO)3] a non-metallocenic organometallic ligand. The catalytic system trans-[(T5-C5H4PPh2)Re(CO)3]PdCl2(NCMe)/PPh3 (1:2 ratio), carbon monoxide and methanol, in the presence of HCl as acidic promoter, showed good catalytic activity, excellent regioselectivity to the branched products and chemoselectivity up to 94%. |
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