Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization

Particle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization.

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Bibliographic Details
Main Authors: Machado,R.A.F., Pinto,J.C., Araújo,P.H.H., Bolzan,A.
Format: Digital revista
Language:English
Published: Brazilian Society of Chemical Engineering 2000
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400004
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Description
Summary:Particle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization.