Triterpenoid saponins from Lippia alba (Mill.) N. E. Brown
Two saponins were isolated from the leaves of Lippia alba. Their structures were established using one- and two-dimensional NMR spectroscopy and mass spectrometry. These new compounds were elucidated as 3-O-β-D-glucopyranosyl-28-O-(α-L-rhamnopyranosyl-(1?3)-β-D-xylopyranosyl-(1?4)-α-L-rhamnopyranosyl-(1?2)-α-L-arabinopyranosyl)-16α,23-dihydroxy-olean-12-en-28-oic acid, named as Lippiasaponin I (2) and as 3-O-β-D-glucopyranosyl-28-O-(α-L-rhamnopyranosyl-(1?3)-β-D-xylopyranosyl-(1?4)-α-L-rhamnopyranosyl-(1?3)-α-L-arabinopyranosyl)-16α,23-dihydroxy-olean-12-en-28-oic acid, named Lippiasaponin II (3).
Main Authors: | , , , , , |
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Format: | Digital revista |
Language: | English |
Published: |
Sociedade Brasileira de Química
2010
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000500023 |
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Summary: | Two saponins were isolated from the leaves of Lippia alba. Their structures were established using one- and two-dimensional NMR spectroscopy and mass spectrometry. These new compounds were elucidated as 3-O-β-D-glucopyranosyl-28-O-(α-L-rhamnopyranosyl-(1?3)-β-D-xylopyranosyl-(1?4)-α-L-rhamnopyranosyl-(1?2)-α-L-arabinopyranosyl)-16α,23-dihydroxy-olean-12-en-28-oic acid, named as Lippiasaponin I (2) and as 3-O-β-D-glucopyranosyl-28-O-(α-L-rhamnopyranosyl-(1?3)-β-D-xylopyranosyl-(1?4)-α-L-rhamnopyranosyl-(1?3)-α-L-arabinopyranosyl)-16α,23-dihydroxy-olean-12-en-28-oic acid, named Lippiasaponin II (3). |
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