Oxidation of chalcogenides using the peroxo complex of molybdenum [MoO(O2)2(H2O)(hmpa)], hmpa = hexamethylphosphoramide
This work reports the oxidation of a variety of selenides, sulfides, tellurides, selenoxides, sulfoxides and telluroxides with [MoO(O2)2(H2O)(hmpa)] [hmpa = (Me2N)3PO] in tetrahydrofuran at 65-70 ºC to produce the corresponding selenones, sulfones and tellurones in high yields.
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Main Authors: | , , |
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Format: | Digital revista |
Language: | English |
Published: |
Sociedade Brasileira de Química
2009
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000700009 |
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Summary: | This work reports the oxidation of a variety of selenides, sulfides, tellurides, selenoxides, sulfoxides and telluroxides with [MoO(O2)2(H2O)(hmpa)] [hmpa = (Me2N)3PO] in tetrahydrofuran at 65-70 ºC to produce the corresponding selenones, sulfones and tellurones in high yields. |
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