Cicloadições [3+4] via cátions oxialílicos: aplicações em sínteses orgânicas
Several methodologies for the generation of oxyallyl cations from polybromoketones and other substrates are discussed. The mechanistic aspect of the [3+4] cycloaddition reaction between these cations and dienes leading to the formation of seven membered ring carbocyclic compounds is presented. Finally, some synthetic applications of the [3+4] cycloaddition are shown.
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Main Authors: | , , |
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Format: | Digital revista |
Language: | Portuguese |
Published: |
Sociedade Brasileira de Química
1997
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421997000100005 |
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Summary: | Several methodologies for the generation of oxyallyl cations from polybromoketones and other substrates are discussed. The mechanistic aspect of the [3+4] cycloaddition reaction between these cations and dienes leading to the formation of seven membered ring carbocyclic compounds is presented. Finally, some synthetic applications of the [3+4] cycloaddition are shown. |
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