Formulas for activity coefficients of individual ions

For chemical calculations with gaseous equilibria and for non-ionic reactions in solution one can calculate in terms of concentrations to a fairly good approximation. However, in dealing with ionic reactions, with certain aspects of kinetics in solution, and with elcetromotive force studies, substitutiion of concentrations for activities is frequently not possible. For this reason it is essential to consider how ionic concentrations can be converted to activities

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Bibliographic Details
Main Authors: Ritsema, C.J., Bloemer, F.
Format: External research report biblioteca
Language:English
Published: I.C.W.
Subjects:ion exchange, soil chemistry, bodemchemie, ionenuitwisseling,
Online Access:https://research.wur.nl/en/publications/formulas-for-activity-coefficients-of-individual-ions
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Description
Summary:For chemical calculations with gaseous equilibria and for non-ionic reactions in solution one can calculate in terms of concentrations to a fairly good approximation. However, in dealing with ionic reactions, with certain aspects of kinetics in solution, and with elcetromotive force studies, substitutiion of concentrations for activities is frequently not possible. For this reason it is essential to consider how ionic concentrations can be converted to activities