Ferric chloride: An excellent reagent for the removal of benzyl ethers in the presence of p-bromobenzoate esters
Anhydrous FeCl3 in dry CH2Cl2 removed benzyl ethers from carbohydrates containing p-bromobenzoate esters, without hydrogenolysis of the bromine atoms. In addition, debenzylations of β-glycopyranosides occurred with simultaneous anomerization or retention of the anomeric configuration.
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| Main Authors: | , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Elsevier
1995-04
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| Subjects: | Ferric chloride, Reagent, Benzyl ethers, p-bromobenzoate esters, |
| Online Access: | http://hdl.handle.net/10261/211860 http://dx.doi.org/10.13039/501100008737 |
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| Summary: | Anhydrous FeCl3 in dry CH2Cl2 removed benzyl ethers from carbohydrates containing p-bromobenzoate esters, without hydrogenolysis of the bromine atoms. In addition, debenzylations of β-glycopyranosides occurred with simultaneous anomerization or retention of the anomeric configuration. |
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