Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine

Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine

The present report is concerned with the synthesis and coordination compounds of 2-amino(N-aminobenzoyl)benzohydrazid e [ABH]. The ligand was characterized by proton NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got -NH2 moiety which is capable of chelation. Therefore, complexes of Ni, Cu, and Zn (II) nitrates were prepared. These complexes were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra showed that the ligand forms complexes through -NH2 moiety, while the elemental analysis suggest M(ABH)(NO3)2 composition of the coordination compounds, ABH acting as bidentate ligand.

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Main Authors: Rehman,Saeed-Ur, Ikram,Muhammad, Rehman,Sadia, Islam,Nazar Ul, Jan,Nazir
Format: Digital revista
Language:English
Published: Sociedad Química de México A.C. 2011
Online Access:http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2011000300006
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spelling oai:scielo:S1870-249X20110003000062013-04-17Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified HydrazineRehman,Saeed-UrIkram,MuhammadRehman,SadiaIslam,Nazar UlJan,Nazir ABH Coordination Compounds The present report is concerned with the synthesis and coordination compounds of 2-amino(N-aminobenzoyl)benzohydrazid e [ABH]. The ligand was characterized by proton NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got -NH2 moiety which is capable of chelation. Therefore, complexes of Ni, Cu, and Zn (II) nitrates were prepared. These complexes were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra showed that the ligand forms complexes through -NH2 moiety, while the elemental analysis suggest M(ABH)(NO3)2 composition of the coordination compounds, ABH acting as bidentate ligand.info:eu-repo/semantics/openAccessSociedad Química de México A.C.Journal of the Mexican Chemical Society v.55 n.3 20112011-09-01info:eu-repo/semantics/articletext/htmlhttp://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2011000300006en
institution SCIELO
collection OJS
country México
countrycode MX
component Revista
access En linea
databasecode rev-scielo-mx
tag revista
region America del Norte
libraryname SciELO
language English
format Digital
author Rehman,Saeed-Ur
Ikram,Muhammad
Rehman,Sadia
Islam,Nazar Ul
Jan,Nazir
spellingShingle Rehman,Saeed-Ur
Ikram,Muhammad
Rehman,Sadia
Islam,Nazar Ul
Jan,Nazir
Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
author_facet Rehman,Saeed-Ur
Ikram,Muhammad
Rehman,Sadia
Islam,Nazar Ul
Jan,Nazir
author_sort Rehman,Saeed-Ur
title Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
title_short Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
title_full Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
title_fullStr Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
title_full_unstemmed Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine
title_sort synthesis and characterization of ni(ii), cu(ii) and zn(ii) tetrahedral transition metal complexes of modified hydrazine
description The present report is concerned with the synthesis and coordination compounds of 2-amino(N-aminobenzoyl)benzohydrazid e [ABH]. The ligand was characterized by proton NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got -NH2 moiety which is capable of chelation. Therefore, complexes of Ni, Cu, and Zn (II) nitrates were prepared. These complexes were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra showed that the ligand forms complexes through -NH2 moiety, while the elemental analysis suggest M(ABH)(NO3)2 composition of the coordination compounds, ABH acting as bidentate ligand.
publisher Sociedad Química de México A.C.
publishDate 2011
url http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2011000300006
work_keys_str_mv AT rehmansaeedur synthesisandcharacterizationofniiicuiiandzniitetrahedraltransitionmetalcomplexesofmodifiedhydrazine
AT ikrammuhammad synthesisandcharacterizationofniiicuiiandzniitetrahedraltransitionmetalcomplexesofmodifiedhydrazine
AT rehmansadia synthesisandcharacterizationofniiicuiiandzniitetrahedraltransitionmetalcomplexesofmodifiedhydrazine
AT islamnazarul synthesisandcharacterizationofniiicuiiandzniitetrahedraltransitionmetalcomplexesofmodifiedhydrazine
AT jannazir synthesisandcharacterizationofniiicuiiandzniitetrahedraltransitionmetalcomplexesofmodifiedhydrazine
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