Synthesis and Characterization of Ni(II), Cu(II) and Zn(II) Tetrahedral Transition Metal Complexes of Modified Hydrazine

The present report is concerned with the synthesis and coordination compounds of 2-amino(N-aminobenzoyl)benzohydrazid e [ABH]. The ligand was characterized by proton NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got -NH2 moiety which is capable of chelation. Therefore, complexes of Ni, Cu, and Zn (II) nitrates were prepared. These complexes were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra showed that the ligand forms complexes through -NH2 moiety, while the elemental analysis suggest M(ABH)(NO3)2 composition of the coordination compounds, ABH acting as bidentate ligand.

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Bibliographic Details
Main Authors: Rehman,Saeed-Ur, Ikram,Muhammad, Rehman,Sadia, Islam,Nazar Ul, Jan,Nazir
Format: Digital revista
Language:English
Published: Sociedad Química de México A.C. 2011
Online Access:http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2011000300006
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