Kinetics of Vacancy Doping in SrTiO3 Studied by in situ Electrical Resistivity

The kinetics of annealing to transform stoichiometric SrTiO3 insulator into a vacancy-doped semiconductor-superconductor was revisited by in situ electrical resistivity measurements. SrTiO3 single crystals were grown by Floating Zone Method. Using a homemade apparatus several electrical resistivity as a function of time were measured at different temperatures, which allows one to study the creation of vacancies during annealing under vacuum. The activation energy for the oxygen vacancies formation/charge doping in SrTiO3 was estimated as 1.4±0.3 eV using solid-state kinetics approach.

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Bibliographic Details
Main Authors: Oliveira,Felipe Souza, Favero,Ana Carolina, Renosto,Sergio Tuan, Luz,Mário Sérgio da, Santos,Carlos Alberto Moreira dos
Format: Digital revista
Language:English
Published: ABM, ABC, ABPol 2018
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000400206
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