Giant reversible magnetocaloric effect in flower-like β-Co(OH)2 hierarchical superstructures self-assembled by nanosheets
A facile hydrothermal strategy is proposed to synthesize flower-like β-Co(OH)2 hierarchical microspherical superstructures with a diameter of 0.5-1.5 μm, which are self-assembled by β-Co(OH)2 nanosheets with the average thickness ranging between 20 and 40 nm. The magnetocaloric effect associated with magnetic phase transitions in Co(OH)2 superstructures has been investigated. A sign change in the magnetocaloric effect is induced by a magnetic field, which is related to a filed-induced transition from the antiferromagnetic to the ferromagnetic state below the Néel temperature. The large reversible magnetic-entropy change -ΔSm (13.4 J/kg K at 15 K for a field change of 5 T) indicates that flower-like Co(OH)2 superstructures is a potential candidate for application in magnetic refrigeration in the low-temperature range.
| Main Authors: | , , , , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
ABM, ABC, ABPol
2014
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| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000100024 |
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