Conversion of sandy tailing from banded iron formation exploitation into glass-ceramic materials

Glass-ceramic materials made of 40.0 wt. (%) of sandy tailing from banded iron formation exploitation and 60 wt. (%) of slag from steelwork were analyzed. Vitrification was obtained by heating the batch samples up to 1400 °C for 1 hour and quenching the melt on a stainless steel plate. Devitrification was obtained by heat-treating the as-quenched glass samples in isothermal conditions at 750 and 1000 °C for 2 hours. FTIR spectroscopy analysis on the devitrified samples indicates a peak shift towards higher wave number with respect to the as-quenched glass because of the crystallization. XRD analysis revealed the presence of crystalline diopside CaMgSi2O6 as the major phase in the glass samples isothermally heat-treated at 1000 °C. Results also indicated that the devitrification at 1000 °C and an incipient devitrification at 750 °C resulted into harder glass-ceramic materials.

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Bibliographic Details
Main Authors: Melo,Valéria Alves Rodrigues de, Lameiras,Fernando Soares, Tolentino,Evandro
Format: Digital revista
Language:English
Published: ABM, ABC, ABPol 2012
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000100003
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