Analysis of the mechanical properties and characterization by solid state 13C NMR of recycled EVA copolymer/silica composites

The incorporation of micrometer sized silica particles on poly (ethylene-co-vinyl acetate) - EVA - residues from the footwear industry was evaluated. The effects of the processing parameters - temperature and mixing ratio - on the mechanical behavior of molded plates of neat recycled EVA and EVA/silica composites were also investigated. The mechanical properties measured by the tensile test, the fractographic analysis by scanning electron microscopy (SEM), and the 13C Nuclear Magnetic Resonance (NMR) showed a reduced EVA to silica compatibility. Therefore, incorporation of untreated silica to recycled EVA copolymer produced a slight decrease on the mechanical performance of EVA/silica composites in respect to neat EVA copolymer. The NMR analysis also shows that the crosslinking process on recycled EVA may be occurring at the carbonyl group.

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Bibliographic Details
Main Authors: Stael,Giovanni Chaves, Rocha,Marisa Cristina Guimarães, Sônia Maria Cabral de,Menezes, d'Almeida,José Roberto Morais, Ruiz,Naira Machado da Silva
Format: Digital revista
Language:English
Published: ABM, ABC, ABPol 2005
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392005000300008
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