Electrochemical Study of Alkynyl Fe(II) Complexes

Electrochemical Study of Alkynyl Fe(II) Complexes

The behaviour of the neutral alkynyl complexes trans-[FeBr(L)(depe)2] (L = -C=C-C(=CH2)Ph 1a, -C=C-CPh2(H) 1b; depe = Et2PCH2CH2PEt2) is studied by cyclic voltammetry and the electrochemical P L and E L ligand parameters for the alkynyl ligands are estimated showing that they behave as very strong net electron-donors.

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Main Authors: Venâncio,Ana I.F., Martins,Luísa M.D.R.S., Pombeiro,Armando J.L.
Format: Digital revista
Language:English
Published: Sociedade Portuguesa de Electroquímica 2003
Online Access:http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000100007
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spelling oai:scielo:S0872-190420030001000072009-01-21Electrochemical Study of Alkynyl Fe(II) ComplexesVenâncio,Ana I.F.Martins,Luísa M.D.R.S.Pombeiro,Armando J.L. alkynyl anodic behaviour electrochemical ligand parameters cyclic voltammetry The behaviour of the neutral alkynyl complexes trans-[FeBr(L)(depe)2] (L = -C=C-C(=CH2)Ph 1a, -C=C-CPh2(H) 1b; depe = Et2PCH2CH2PEt2) is studied by cyclic voltammetry and the electrochemical P L and E L ligand parameters for the alkynyl ligands are estimated showing that they behave as very strong net electron-donors.info:eu-repo/semantics/openAccessSociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.21 n.1 20032003-01-01info:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000100007en
institution SCIELO
collection OJS
country Portugal
countrycode PT
component Revista
access En linea
databasecode rev-scielo-pt
tag revista
region Europa del Sur
libraryname SciELO
language English
format Digital
author Venâncio,Ana I.F.
Martins,Luísa M.D.R.S.
Pombeiro,Armando J.L.
spellingShingle Venâncio,Ana I.F.
Martins,Luísa M.D.R.S.
Pombeiro,Armando J.L.
Electrochemical Study of Alkynyl Fe(II) Complexes
author_facet Venâncio,Ana I.F.
Martins,Luísa M.D.R.S.
Pombeiro,Armando J.L.
author_sort Venâncio,Ana I.F.
title Electrochemical Study of Alkynyl Fe(II) Complexes
title_short Electrochemical Study of Alkynyl Fe(II) Complexes
title_full Electrochemical Study of Alkynyl Fe(II) Complexes
title_fullStr Electrochemical Study of Alkynyl Fe(II) Complexes
title_full_unstemmed Electrochemical Study of Alkynyl Fe(II) Complexes
title_sort electrochemical study of alkynyl fe(ii) complexes
description The behaviour of the neutral alkynyl complexes trans-[FeBr(L)(depe)2] (L = -C=C-C(=CH2)Ph 1a, -C=C-CPh2(H) 1b; depe = Et2PCH2CH2PEt2) is studied by cyclic voltammetry and the electrochemical P L and E L ligand parameters for the alkynyl ligands are estimated showing that they behave as very strong net electron-donors.
publisher Sociedade Portuguesa de Electroquímica
publishDate 2003
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000100007
work_keys_str_mv AT venancioanaif electrochemicalstudyofalkynylfeiicomplexes
AT martinsluisamdrs electrochemicalstudyofalkynylfeiicomplexes
AT pombeiroarmandojl electrochemicalstudyofalkynylfeiicomplexes
_version_ 1756001840570302464

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