Electrochemical Study of Alkynyl Fe(II) Complexes
The behaviour of the neutral alkynyl complexes trans-[FeBr(L)(depe)2] (L = -C=C-C(=CH2)Ph 1a, -C=C-CPh2(H) 1b; depe = Et2PCH2CH2PEt2) is studied by cyclic voltammetry and the electrochemical P L and E L ligand parameters for the alkynyl ligands are estimated showing that they behave as very strong net electron-donors.
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| Main Authors: | , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedade Portuguesa de Electroquímica
2003
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| Online Access: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042003000100007 |
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