CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

ABSTRACT In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H⋯F, H⋯π and H⋯Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.

Bibliographic Details

Main Authors:	Maharramov,Abel M., Duruskari,Gulnara SH., Mammadova,Gunay Z., Khalilov,Ali N., Aslanova,Javahir M., Cisterna,Jonathan, Cárdenas,Alejandro, Brito,Iván
Format:	Digital revista
Language:	English
Published:	Sociedad Chilena de Química 2019
Online Access:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072019000204441
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