ONLINE MULTI-STAGE MEMBRANE FILTRATION OF SYNTHETIC POLYDISPERSED WATER-SOLUBLE POLYMERS WITH UV VISIBLE ABSORPTION AS A MODE FOR THEIR DETECTION
This paper reports the application of online membrane filtration with UV visible absorption as a mode of polydispersed substances detection for poly(acryloyl morpholine-co-2-acrylamido-2-methyl-1-propane sulfonic acid), poly[2-acrylamido-2-methyl-1-propane sulfonic acid-co-(3-acryloylamidopropyl) trimethylammonium nitrate), and poly(vinyl alcohol-co-crotonic acid) 10 % of crotonic acid which can be used in medicine and technology. The mass balance in all the cases was not below 100 ± 7 %. The calibration curve are linear at 1opt , 245, 230, and 220 nm in the interval 0.1-4.0 mg/mL, 0.2-3.0 mg/mL and 0.2-6.0 mg/mL, respectively. It was also used the combination of microfiltration, MF, and gel permeation chromatography, GPC to provide more complete information about the molecular weight distribution of the obtained fractions.
Main Authors: | , , , , , |
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Format: | Digital revista |
Language: | English |
Published: |
Sociedad Chilena de Química
2010
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Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000100013 |
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