SYNTHESIS, CHARACTERIZATION OF A NEW CARBONYLATED ZIRCONIUM METALLOCENE USING A DICHLORO-ZIRCONOCENE DERIVED FROM PARTIALLY ALKYLATED S-INDACENE
This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.
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| Main Authors: | , , , , , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2009
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014 |
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