SYNTHESIS AND STRUCTURE OF DICARBONYLDICHLORO{2-(DIPHENYLPHOSPHINEOXIDE)PYRIDINE}RUTHENIUM(II)

Reaction of the dinuclear complex [{Ru(CO)3Cl2}J with the Hgand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k²-PyPOPh2-N,0)(CO)2Cl2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structure was determined by single-crystal X-ray diffraction.

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Bibliographic Details
Main Authors: DÍAZ,OSCAR, MEDINA,SOLEDAD, VALDERRAMA,MAURICIO, LAHOZ,FERNANDO J, MARTÍN,M. LUISA
Format: Digital revista
Language:English
Published: Sociedad Chilena de Química 2008
Online Access:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072008000200007
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