Oxo and oxofree rhenium(V) complexes with N,O-donor Schiff bases
The reaction between cis-[ReV O2I(PPh3)2] and H3duo (N-(2-hydroxybenzylidene)-5-amino-1,3-dimethyl uracil) led to the formation of the oxofree, imido compound, trans-[ReV(ddd)(Hduo)(PPh3)2]I (1) (H2ddd = 5,6-diamino-1,3-dimethyluracil). An oxo complex, cis-[ReV(bcp)OCl2(PPh3)](2) [Hbcp = N-(2-hydroxybenzylidene)-benzothiazole] was isolated from the reaction of trans-[ReO V Cl3(PPh3)2]with Hbcp. The crystal structures of the compounds were determined by single crystal X-ray diffraction.
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| Main Authors: | , , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
The South African Chemical Institute
2012
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| Online Access: | http://www.scielo.org.za/scielo.php?script=sci_arttext&pid=S0379-43502012000100028 |
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