High-pressure cloud point data for the system glycerol + olive oil + n-butane + AOT

This work reports high-pressure cloud point data for the quaternary system glycerol + olive oil + n-butane + AOT surfactant. The static synthetic method, using a variable-volume view cell, was employed for obtaining the experimental data at pressures up to 27 MPa. The effects of glycerol/olive oil concentration and surfactant addition on the pressure transition values were evaluated in the temperature range from 303 K to 343 K. For the system investigated, vapor-liquid (VLE), liquid-liquid (LLE) and vapor-liquid-liquid (VLLE) equilibrium were recorded. It was experimentally observed that, at a given temperature and surfactant content, an increase in the concentration of glycerol/oil ratio led to a pronounced increase in the slope of the liquid-liquid coexistence curve. A comparison with results reported for the same system but using propane as solvent showed that much lower pressure transition values are obtained when using n-butane.

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Bibliographic Details
Main Authors: Bender,J. P., Junges,A., Franceschi,E., Corazza,F. C., Dariva,C., Oliveira,J. Vladimir, Corazza,M. L.
Format: Digital revista
Language:English
Published: Brazilian Society of Chemical Engineering 2008
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322008000300014
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