Removal of phenol by enzymatic oxidation and flotation

This work presents a process for phenol removal comprising a reaction step in which phenol is polymerized in the presence of an enzyme followed by a separation step involving dissolved air flotation (DAF). A crude preparation from horseradish roots was used as a low purity source of the enzyme horseradish peroxidase (HRP). The technical feasibility of the process was studied at bench scale using 1 to 10 mM synthetic phenol solutions. Experimental results showed the potential of the proposed technique. A phenol conversion higher than 99 % was observed at the polymerization step and an efficiency higher than 94 % was achieved at the separation stage. Despite the use of a low purity source of HRP, which increases the input of organic matter, the chemical oxygen demand (COD) decreased by 50 %.

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Bibliographic Details
Main Authors: Wilberg,K.Q., Nunes,D.G., Rubio,J.
Format: Digital revista
Language:English
Published: Brazilian Society of Chemical Engineering 2000
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322000000400055
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