Nanocomposite polymer electrolytes based on poly(oxyethylene) and cellulose whiskers

Solid lithium-conducting nanocomposite polymer electrolytes based on poly(oxyethylene) (POE) were prepared from high aspect ratio cellulosic whiskers and lithium imide salt, LiTFSI. The cellulosic whiskers were extracted from tunicate -a sea animal- and consisted of slender parallelepiped rods that have an average length around 1 µm and a width close to 15 nm. High performance nanocomposite electrolytes were obtained. The filler provided a high reinforcing effect while a high level of ionic conductivity was retained with respect to unfilled polymer electrolytes. Cross-linking and plasticizing of the matrix as well as preparation of the composites from an organic medium were also investigated.

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Bibliographic Details
Main Authors: Samir,My Ahmed Saïd Azizi, Alloin,Fannie, Sanchez,Jean-Yves, Dufresne,Alain
Format: Digital revista
Language:English
Published: Associação Brasileira de Polímeros 2005
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200009
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