SR-TXRF detection limit reduction using thin polymer film substrates

Three different substrates for the analysis of liquid samples by Total Reflection X-Ray Fluorescence with Synchrotron Radiation (SR-TXRF) were investigated and compared: Lucite (Perspex), Kimfoil and Mylar. Dry targets were prepared by pipetting 5 mul aliquotes of the liquid samples (synthetic standards and fresh water samples) on the different substrates. A five fold reduction of the continuous background and a corresponding reduction of the elementary detection limits were observed when thin polymer film substrates were used instead of the common thick Perspex substrate.

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Bibliographic Details
Main Authors: Poli,V.S., Tabacniks,M.H., Rizzutto,M.A., Added,N., Espinoza-Quiñones,F.R., Palácio,S.M.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Física 2004
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332004000500072
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