Polymer brush modified electrode with switchable selectivity triggered by pH changes enhanced by gold nanoparticles

In this work, a sensor was built up with smart material based on polymer brush and gold nanoparticles. The modified electrode functionalized with polyacrylic acid (PAA) tethered to indium tin oxide (ITO) and covered with gold nanoparticle (ITO/PAA/Au) demonstrated switchable interfacial properties discriminating different pHs. The switchable electrochemical and plasmonic process was characterized by cyclic voltammetry (CV), electrochemistry impedance spectroscopy (EIS), and localized surface plasmon resonance (LSPR).

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Bibliographic Details
Main Authors: Sempionatto,Juliane R., Recco,Lucas C., Pedrosa,Valber A.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2014
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000300007
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