Highly regioselective synthesis of novel 1,4'-bipyrazoles

Novel 1,4'-bipyrazoles were synthesized via highly regioselective cyclocondensation reactions of β-dimethylaminoenones with hydrazine monohydrate, tert-butylhydrazine hydrochloride, phenylhydrazine hydrochloride or carboxymethylhydrazine. X-ray diffraction technique was used in the elucidation of the regiochemistry of the β-dimethylaminoenaminones and of the 1,4'-bipyrazoles. 1,4'-Bipyrazolylisoxazoles were also reported.

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Bibliographic Details
Main Authors: Martins,Marcos A. P., Fiss,Gabriela F., Frizzo,Clarissa P., Rosa,Fernanda A., Bonacorso,Helio G., Zanatta,Nilo
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2010
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000200008
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