Vinylic tellurides as precursors in a stereoselective and convergent route to Z-enynes and Z-trisubstituted enediynes
Vinylic tellurides of Z configuration are transformed into higher order Z-vinyl cyanocuprates by transmetallation with higher order lithium dimethyl- or n-butyl(thienyl)cyanocuprates. Reaction of the obtained Z-vinyl cyanocuprates with zinc chloride gives presumably mixed zinc-copper species which react with bromoalkynes leading to enynes and enediynes with retention of the Z double bond configuration.
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2004
|
| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000300004 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|