Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes

Oxidative coupling of 2-methoxy-1,4-benzoquinone and arenes in acetic acid gives methoxyaryl-substituted 1,4-benzoquinones. The reaction is effectively catalyzed by a Pd(OAc)2/heteropoly acid (H9PMo6V6O40 ) redox system with dioxygen as the final oxidant.

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Bibliographic Details
Main Authors: Oliveira,Rosilene A. de, Gusevskaya,Elena V., Carazza,Fernando
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2002
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100018
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