Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
Cohalogenation of (R)-limonene and (R)-carvomenthene with I2/H2O/Cu(OAc)2·H 2O in aqueous dioxane followed by base treatment produced stereospecifically the corresponding trans-epoxides. Same methodology of cohalogenation applied to related monoterpenic unsaturated alcohols produced pinol derivatives [from (5R)-cis-carveol and (S)-alpha-terpineol] or iodohydrins [from (S)-perillyl alcohol and (5R)-trans-carveol].
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| Main Authors: | , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2000
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| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000400010 |
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