Electrochemical Behavior of 4-keto Isophorone in Non-Aqueous Medium in the Presence of Carbon Dioxide
The kinetics of the slow coupling of CO2 with the anion-radical of 4-keto isophorone (4KI) in acetonitrile and on a gold/amalgamated electrode has been analyzed by using cyclic voltammetry and double potential step chronoamperometry. The coupling rate is estimated as 0.35 s-1 and the electrode mechanism at slow sweep rates (nu < 1 V s-1) is predominantly DISP1.
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| Main Authors: | , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
1998
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| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000200007 |
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