A new di-m-sulfate complex as a model of purple acid phosphatase-sulfate complexes

The synthesis, X-ray crystal structure, electrochemical and spectroscopic properties of NH4Fe2III(bbpmp)(m-SO4)2 1 where bbpmp is the anion of 2,6-bis(2-hydroxy- benzyl)(2-pyridylmethyl)-amino-methyl-4-methylphenol, are reported; this is the first example of a (m-phenolate)(m-SO4)2 complex, with a relevant N,O-donor ligand, as a synthethic analogue for the purple acid phosphatases-sulfate complexes.

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Bibliographic Details
Main Authors: Brito,Marcos A. de, Neves,Ademir, Vencato,Ivo, Zucco,César, Drago,Valderes, Griesar,Klaus, Haase,Wolfgang
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 1997
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000500003
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