Self-assembly of supermolecular species directed by hydrogen bonding and aromatic π-π stacking interactions
A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure.
Main Authors: | , , |
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Format: | Digital revista |
Language: | English |
Published: |
Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
2008
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702008000200002 |
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