Temperature measurements by oh lif and chemiluminescence kinetic modeling for ethanol flames
OH LIF-thermometry was applied to premixed ethanol flames at atmospheric pressure in a burner for three flame conditions. Flame temperatures were simulated from energy equation with PREMIX code of CHEMKIN software package for comparison. A kinetic modeling based on a model validated through chemiluminescence measurements and on a set of reactions for nitrogen chemistry was evaluated. Marinov's mechanism was also tested. Sensitivity analysis was performed for fuel-rich flame condition with Φ = 1.34. Simulated temperatures from both reaction mechanisms evaluated were higher than experimental values. However, the proposed kinetic modeling resulted in temperature profiles qualitatively very close to the experimental.
Main Authors: | , , , , |
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Format: | Digital revista |
Language: | Portuguese |
Published: |
Sociedade Brasileira de Química
2009
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000800017 |
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