Branqueamento de polpa celulósica kraft de eucalipto com peróxido ácido ativado por molibdênio
Optimum conditions to run the P Mo stage for bleaching eucalyptus kraft pulp were 90 ºC, pH 3.5, 2 h, 0.1 kg/t Mo and 5 kg/t H2O2. The P Mo stage efficiency increased with decreasing pH (1.5-5.5) and increasing temperature (75-90 ºC), time (2-4 h), and hydrogen peroxide (3-10 kg/t) and molybdenum concentration (0.1-0.4 kg/t). The implementation of the P Mo stage, as replacement for the A stage, decreased total active chlorine demand of the OAZDP sequence by 6 kg/t to reach 90% ISO, both in laboratory and mill scale. Such practice resulted in decreased bleaching chemical costs to produce fully bleached pulp of 90% ISO.
Main Authors: | , , , , , |
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Format: | Digital revista |
Language: | Portuguese |
Published: |
Sociedade Brasileira de Química
2009
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Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500002 |
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