Branqueamento de polpa celulósica kraft de eucalipto com peróxido ácido ativado por molibdênio

Optimum conditions to run the P Mo stage for bleaching eucalyptus kraft pulp were 90 ºC, pH 3.5, 2 h, 0.1 kg/t Mo and 5 kg/t H2O2. The P Mo stage efficiency increased with decreasing pH (1.5-5.5) and increasing temperature (75-90 ºC), time (2-4 h), and hydrogen peroxide (3-10 kg/t) and molybdenum concentration (0.1-0.4 kg/t). The implementation of the P Mo stage, as replacement for the A stage, decreased total active chlorine demand of the OAZDP sequence by 6 kg/t to reach 90% ISO, both in laboratory and mill scale. Such practice resulted in decreased bleaching chemical costs to produce fully bleached pulp of 90% ISO.

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Bibliographic Details
Main Authors: Rabelo,Marcos Sousa, Silva,Vanessa Lopes, Barros,Denise Pires de, Colodette,Jorge Luiz, Sacon,Vera Maria, Silva,Marcelo Rodrigues da
Format: Digital revista
Language:Portuguese
Published: Sociedade Brasileira de Química 2009
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500002
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