Screening of pesticide residues in honeybee wax comb by LC-ESI-MS/MS. A pilot study
A developed multi-residue method using microflow-LC-ESI-QqQ-MS provided a wide-scope analysis for medium-polar and polar pesticide residues (120 compounds including breakdown products). Honeybee wax comb samples were extracted using a generic QuEChERS based procedure. Acceptable recoveries at concentration levels of 5 and 50 μg kg−1 were within the 70–120% range with an associated precision RSD <20%. The LOQ values were mostly 5 μg kg−1 for almost all pesticides. Aprox. 31 of 120 LC-amenable pesticides tested (25.8%) were detected in a pilot study of 60 samples. Pesticide residues detected using the proposed method were: the breakdown products of amitraz, DMPF and DMF, an acaricide used for Varroa mite control, with a range of concentration from 5 to 464 μg kg−1 (sum of DMPF + DMF), organophosphate insecticides from 1 to 464 μg kg−1, acaricides at concentrations > 9 μg kg−1; fungicides at concentrations ranging from 1 to 23 μg kg−1. The number of positive detections due to herbicides was lower as expected and at a lower level of concentration, from 1 to 5.9 μg kg−1.
| Main Authors: | , , , , |
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| Format: | info:ar-repo/semantics/artículo biblioteca |
| Language: | eng |
| Published: |
2016-11
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| Subjects: | Abeja Melífera, Cera de Abeja, Productos de la Colmena, Residuos de Plaguicidas, Técnicas de Trazadores, Honey Bees, Beeswax, Hive Products, Pesticide Residues, Tracer Techniques, LC-ESI-MS/MS, |
| Online Access: | https://www.sciencedirect.com/science/article/pii/S004565351630892X?via%3Dihub http://hdl.handle.net/20.500.12123/3521 https://doi.org/10.1016/j.chemosphere.2016.07.008 |
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