A process for the preparation of a tertiary perester

The invention relates to a process for the preparation of a tertiary perester by contacting an acyl compound with a tertiary hydroperoxide in the presence of an enzyme catalyst. The acyl compound has the formula R1[C(O)OR2]n, wherein R1 is a linear or branched, saturated or unsaturated C1-C22 group, optionally containing one or more hetero atoms, R2 represents hydrogen or has the same meaning as described for R1, and n is 1-5, or a polyalcohol ester of R1C(O)OH, wherein R1 has the same meaning as described above. The tertiary hydroperoxide has the formula [HOOCR3R3]mR4, wherein R3 represents either a methyl or an ethyl group, R4 has the same meaning as described for R1, and m is 1-5.

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Bibliographic Details
Main Authors: Tammer, M.C., Meijer, J., Cuperus, F.P., Derksen, J.T.P., Kramer, G.F.H.
Format: Patent biblioteca
Language:English
Subjects:Life Science,
Online Access:https://research.wur.nl/en/publications/a-process-for-the-preparation-of-a-tertiary-perester
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