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Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions
Nineteen bioactive highly functionalized 6,6a-dihydroisoindolo[2,1-a]quinolin-11(5H)-one derivatives were easily prepared in good yield without solvent using catalytic amorphous milled cellulose sulfonic acid (AMCell-SO3H), substituted anilines, propenyl-phenols, and phthaldehydic acid. The cascade reaction gave high regioselectivity and diastereoselectivity.
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| Format: | Artículo científico biblioteca |
| Language: | eng |
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2014-04-30
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| Subjects: | Biología vegetal, Aceites vegetales, Productos químicos, Biología molecular, Biotecnología, Aceites esenciales, Tecnología química, Química agrícola, |
| Online Access: | http://repositorio.colciencias.gov.co/handle/11146/34169 |
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dig-minciencias-co-20.500.14143-341692023-11-29T12:38:17Z Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions Merchan Arenas, Diego Rolando Kouznetsov, Vladimir V. Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola Nineteen bioactive highly functionalized 6,6a-dihydroisoindolo[2,1-a]quinolin-11(5H)-one derivatives were easily prepared in good yield without solvent using catalytic amorphous milled cellulose sulfonic acid (AMCell-SO3H), substituted anilines, propenyl-phenols, and phthaldehydic acid. The cascade reaction gave high regioselectivity and diastereoselectivity. Departamento Administrativo de Ciencia, Tecnología e Innovación [CO] Colciencias 5507-543-31904 Programa: Bioprospección y desarrollo de ingredientes naturales para las industrias cosmética, farmacéutica y de productos de aseo con base en la biodiversidad colombiana no 2019-04-01T00:03:12Z 2019-04-01T00:03:12Z 2014-04-30 info:eu-repo/date/embargoEnd/2024-01-31 Artículo científico info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article http://repositorio.colciencias.gov.co/handle/11146/34169 Contiene 37 referencias bibliográficas. Véase documento adjunto 10.1021/jo500516c eng Programa: Bioprospección y desarrollo de ingredientes naturales para las industrias cosmética, farmacéutica y de productos de aseo con base en la biodiversidad colombiana. La publicación completa está disponible en : <a href="http://repositorio.colciencias.gov.co/handle/11146/34163" target="blank">http://repositorio.colciencias.gov.co/handle/11146/34163</a> info:eu-repo/semantics/embargoedAccess pdf 7 páginas application/pdf Colombia The Journal of Organic Chemistry 2014, 79, 5327−5333 |
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| component |
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| databasecode |
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| tag |
biblioteca |
| region |
America del Sur |
| libraryname |
Centro de Documentación y Biblioteca de MINCIENCIAS de Colombia |
| language |
eng |
| topic |
Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola |
| spellingShingle |
Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola Merchan Arenas, Diego Rolando Kouznetsov, Vladimir V. Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| description |
Nineteen bioactive highly functionalized 6,6a-dihydroisoindolo[2,1-a]quinolin-11(5H)-one derivatives were easily prepared in good yield without solvent using catalytic amorphous milled cellulose sulfonic acid (AMCell-SO3H), substituted anilines, propenyl-phenols, and phthaldehydic acid. The cascade reaction gave high regioselectivity and diastereoselectivity. |
| format |
Artículo científico |
| topic_facet |
Biología vegetal Aceites vegetales Productos químicos Biología molecular Biotecnología Aceites esenciales Tecnología química Química agrícola |
| author |
Merchan Arenas, Diego Rolando Kouznetsov, Vladimir V. |
| author_facet |
Merchan Arenas, Diego Rolando Kouznetsov, Vladimir V. |
| author_sort |
Merchan Arenas, Diego Rolando |
| title |
Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| title_short |
Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| title_full |
Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| title_fullStr |
Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| title_full_unstemmed |
Diastereoselective Synthesis of Dihydroisoindolo[2,1‑a]quinolin-11- ones by Solvent-Free AMCell-SO3H‑Catalyzed Imino Diels−Alder/Intramolecular Amide Cyclization Cascade Reactions |
| title_sort |
diastereoselective synthesis of dihydroisoindolo[2,1‑a]quinolin-11- ones by solvent-free amcell-so3h‑catalyzed imino diels−alder/intramolecular amide cyclization cascade reactions |
| publishDate |
2014-04-30 |
| url |
http://repositorio.colciencias.gov.co/handle/11146/34169 |
| work_keys_str_mv |
AT merchanarenasdiegorolando diastereoselectivesynthesisofdihydroisoindolo21aquinolin11onesbysolventfreeamcellso3hcatalyzediminodielsalderintramolecularamidecyclizationcascadereactions AT kouznetsovvladimirv diastereoselectivesynthesisofdihydroisoindolo21aquinolin11onesbysolventfreeamcellso3hcatalyzediminodielsalderintramolecularamidecyclizationcascadereactions |
| _version_ |
1798163047308591104 |