Use of C-18 reverse-phase cartridges for estimation of metal complexation by a residue from olive oil industry
Formation of complexes between Cu and organic polymers present in olive mill wastewater (OMW) is shown to be a cause of metal solubilization by the residue, using C-18 reverse-phase cartridges (RPC) for separating the complexed metal. Nearly 100% of the metal released from a polluted river sediment by OMW solutions is retained by the cartridges. The proportion of Cu retained by the cartridges is somewhat lower (50-80%), if the OMW solution initially contains Cu. About 70-80% of Cu released by OMW from a soil column previously loaded with high doses of metal is also retained by the cartridges. Incomplete Cu retentions are not thought to be due to a lack of efficiency of RPC in immobilizing Cu complexes, but to the formation of an equilibrium between free and complexed forms of the metal.
| Main Authors: | , , |
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| Format: | artículo biblioteca |
| Language: | English |
| Published: |
1997
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| Online Access: | http://hdl.handle.net/10261/66183 |
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