The nature of black stains in Lascaux Cave, France, as revealed by surface-enhanced Raman spectroscopy

We used surface-enhanced Raman spectroscopy to investigate the chemical composition of the black stains threatening the rock-art paintings of Lascaux Cave, Montignac, France. The stains are mainly composed of melanin from the fungus Ochroconis sp. and the faecal pellets of the collembolan Folsomia candida. Surface-enhanced Raman spectroscopy is a useful technique for revealing the structure of unknown macromolecules in cultural heritage research. Copyright © 2011 John Wiley & Sons, Ltd. The chemical composition of the black stains threatening the rock-art paintings of Lascaux Cave, Montignac, France was studied using surface-enhanced Raman spectroscopy (SERS). The stains are mainly composed of the melanin from the fungus Ochroconis sp. and the faecal pellets of the collembolan Folsomia candida. SERS is a useful technique for revealing the structure of unknown macromolecules in cultural heritage research.

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Bibliographic Details
Main Authors: Martín Sánchez, Pedro Mª, Sánchez-Cortés, Santiago, López-Tobar, Eduardo, Jurado, Valme, Bastian, Fabiola, Alabouvette, Claude, Sáiz-Jiménez, Cesáreo
Format: artículo biblioteca
Language:English
Published: John Wiley & Sons 2012
Online Access:http://hdl.handle.net/10261/58805
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