The microbiological transformation of the diterpenes dehydroabietanol and teideadiol by Mucor plumbeus
The microbiological transformation of dehydroabietanol (18-hydroxy-dehydroabietane) by Mucor plumbeus led to 2a,18-dihydroxy-abieta-8,11,13,15-tetraene, 2a,15-dihydroxy-15-methoxy-dehydroabietanol, 7B-hydroxy-2-oxo-dehydroabietanol, 15-hydroxy-2-oxo-dehydroabietanol and 15,16-dihidroxy-2-oxo-dehydroabietanol, whilst that of teideadiol (1a,18-dihydroxy-dehydroabietane) gave 2a-hydroxy-teideadiol, 7a-hydroxy-teideadiol and 7B-hydroxy-teideadiol. Thus, 2a-and 7B-hydroxylation occur in both biotransformations and the 15-hydroxylation is inhibited in the biotransformation of teideadiol by the presence of a 1a-alcohol.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Elsevier
2003
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| Subjects: | Mucor plumbers, Biotransformations, Diterpenes, Dehydroabietanol, Teideadiol, |
| Online Access: | http://hdl.handle.net/10261/21977 |
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