Tetralkylammonium permanganate epoxidation of an uncreactive double bond by an intramolecular oxygen-atom transfer process

The ammonium permanganate oxidation of a tricyclic, rigid diene gives the mono- dihydroxylated compound together with the diol- epoxide derivative. The epoxidation involves an intramolecular oxygen- atom transfer process from the anchored manganese (V) diester to the second double bond.

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Bibliographic Details
Main Authors: Robles Caychoa, Juana, García-Tellado, Fernando, Armas, Pedro de, Marrero-Tellado, José Juan
Format: artículo biblioteca
Language:English
Published: Chemical Society of Japan 1998
Online Access:http://hdl.handle.net/10261/21803
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