The biotransformation of 18-hydroxy-9-epi-ent-pimara-7,15-diene by Gibberella fujikuroi

Incubation of 18-hydroxy-9-epi-ent-pimara-7,15-diene with the fungus Gibberella fujikuroi gave the compounds 18-hydroxy.7a,8a-epoxy-9-epi-ent-pimara-15-ene, 18-hydroxy-7-oxo-ent-pimara-15-ene, 6$,18-dihydroxy-7a,8a-epoxy-9-epi-ent-pimara-15-ene, 9$,18-dihydroxy-7a,8a-epoxy-ent-pimara-15-ene and 6$,14a,18-trihydroxy-9-epi-ent-pimara-7,15-diene. Oxidation of C-19, which is characteristic of the biosynthesis pathway of the gibberellins is not produced.

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Bibliographic Details
Main Authors: Fraga, Braulio M., Hernández, Melchor G., González, Pedro, Chamy, María C., Garbarino, Juan A.
Other Authors: Fondo Nacional de Desarrollo Científico y Tecnológico (Chile)
Format: artículo biblioteca
Language:English
Published: Elsevier 2000
Subjects:Gibberella fujikuroi, Microbiological transformation, Diterpenes, 18-Hydroxy-9-epi-ent-pimara-7,15-diene, Hydroxylation, Epoxidation,
Online Access:http://hdl.handle.net/10261/21526
http://dx.doi.org/10.13039/501100002850
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