pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes
Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Royal Society of Chemistry (UK)
2011-10-10
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| Subjects: | Rhenium(i) complexes, Epimerization, Dynamic stereoinduction, |
| Online Access: | http://hdl.handle.net/10261/212896 http://dx.doi.org/10.13039/501100004837 http://dx.doi.org/10.13039/501100014180 |
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