Chiral Guests and Their Ghosts in Reversibly Assembled Hosts

Achiral building blocks form nonracemic, chiral capsular hosts with enantioselective molecular recognition properties. The chirality is imprinted by a chiral guest template, and persists for hours in organic solvents after the guest has been removed. The exchange equilibria are depicted, with the guest exchanges shown by the horizontal equilibria and monomer exchanges by the vertical equilibria.

Saved in:
Bibliographic Details
Main Authors: Rivera, José M., Craig, Stephen L., Martín, Tomás, Rebek, Julius Jr.
Other Authors: National Institutes of Health (US)
Format: artículo biblioteca
Language:English
Published: Wiley-VCH 2000-06-14
Subjects:Chirality, Host–guest chemistry, Imprinting, Molecular recognition,
Online Access:http://hdl.handle.net/10261/211781
http://dx.doi.org/10.13039/100000002
Tags: Add Tag
No Tags, Be the first to tag this record!