The cis-2-alkyl-3-oxy-tetrahydropyran unit as a building block for new ionophores with C2-symmetry
The use of cis-2-alkyl-3-oxy-tetrahydropyran unit is reported as a novel structure for the design and synthesis of a new type of ionophore with C2-symmetry. The synthesis of five macrolides and their complexation properties were investigated. The template effect as an effective tool to improve the selectivity and yield in the macrolactonization process is described. The cis-2-alkyl-3-oxy-tetrahydropyran unit as a novel structure for the design and synthesis of a new type of ionophore with C2-symmetry is reported. The synthesis of five macrolides and their complexation properties were investigated.
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| Main Authors: | , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Elsevier
2004-06-28
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| Subjects: | Ionophores, Lariat ethers, Template effect, |
| Online Access: | http://hdl.handle.net/10261/211708 http://dx.doi.org/10.13039/501100006280 |
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