Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines

Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines

Transition metal-free radical arylation of heteroarenes is achieved at room temperature by simply adding aqueous sodium carbonate to a solution of the corresponding heteroarene and arenediazonium salt, which can even be formed in situ. Such an easy, inexpensive and mild methodology has been optimized and applied to the expeditious modification of interesting molecular cores like naphthylimide or bisthienylcyclopentenes.

Saved in:
Bibliographic Details
Main Authors: Monzón, Diego M., Santos, Tanausú, Pinacho Crisóstomo, Fernando R., Martín, Víctor S., Carrillo Fumero, Romen
Other Authors: European Commission
Format: artículo biblioteca
Published: Wiley-VCH 2018-02-02
Subjects:Heterocycles, Dyes/pigments, Diazo compounds, C−C coupling, Radical reactions,
Online Access:http://hdl.handle.net/10261/183311
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100000780
Tags: Add Tag
No Tags, Be the first to tag this record!
id dig-ipna-es-10261-183311
record_format koha
spelling dig-ipna-es-10261-1833112020-12-11T08:57:23Z Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines Monzón, Diego M. Santos, Tanausú Pinacho Crisóstomo, Fernando R. Martín, Víctor S. Carrillo Fumero, Romen European Commission Ministerio de Economía y Competitividad (España) Heterocycles Dyes/pigments Diazo compounds C−C coupling Radical reactions Transition metal-free radical arylation of heteroarenes is achieved at room temperature by simply adding aqueous sodium carbonate to a solution of the corresponding heteroarene and arenediazonium salt, which can even be formed in situ. Such an easy, inexpensive and mild methodology has been optimized and applied to the expeditious modification of interesting molecular cores like naphthylimide or bisthienylcyclopentenes. This work has been funded by Ministerio de Economía y Competitividad‐MINECO (CTQ2015‐73234‐JIN and CTQ2014‐56362‐C2‐1‐P), co‐financed by the European Regional Development Fund (ERDF). D. M. M. thanks MINECO for a FPI fellowship. Peer Reviewed 2019-06-04T14:43:18Z 2019-06-04T14:43:18Z 2018-02-02 2019-06-04T14:43:18Z artículo http://purl.org/coar/resource_type/c_6501 doi: 10.1002/asia.201701585 e-issn: 1861-471X issn: 1861-4728 Chemistry - An Asian Journal 13(3): 325-333 (2018) http://hdl.handle.net/10261/183311 10.1002/asia.201701585 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100000780 #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-73234-JIN; /CTQ2014-56362-C2-1-P Postprint https://doi.org/10.1002/asia.201701585 Sí none Wiley-VCH
institution IPNA ES
collection DSpace
country España
countrycode ES
component Bibliográfico
access En linea
databasecode dig-ipna-es
tag biblioteca
region Europa del Sur
libraryname Biblioteca del IPNA España
topic Heterocycles
Dyes/pigments
Diazo compounds
C−C coupling
Radical reactions
Heterocycles
Dyes/pigments
Diazo compounds
C−C coupling
Radical reactions
spellingShingle Heterocycles
Dyes/pigments
Diazo compounds
C−C coupling
Radical reactions
Heterocycles
Dyes/pigments
Diazo compounds
C−C coupling
Radical reactions
Monzón, Diego M.
Santos, Tanausú
Pinacho Crisóstomo, Fernando R.
Martín, Víctor S.
Carrillo Fumero, Romen
Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
description Transition metal-free radical arylation of heteroarenes is achieved at room temperature by simply adding aqueous sodium carbonate to a solution of the corresponding heteroarene and arenediazonium salt, which can even be formed in situ. Such an easy, inexpensive and mild methodology has been optimized and applied to the expeditious modification of interesting molecular cores like naphthylimide or bisthienylcyclopentenes.
author2 European Commission
author_facet European Commission
Monzón, Diego M.
Santos, Tanausú
Pinacho Crisóstomo, Fernando R.
Martín, Víctor S.
Carrillo Fumero, Romen
format artículo
topic_facet Heterocycles
Dyes/pigments
Diazo compounds
C−C coupling
Radical reactions
author Monzón, Diego M.
Santos, Tanausú
Pinacho Crisóstomo, Fernando R.
Martín, Víctor S.
Carrillo Fumero, Romen
author_sort Monzón, Diego M.
title Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
title_short Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
title_full Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
title_fullStr Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
title_full_unstemmed Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
title_sort mild-base-promoted arylation of (hetero)arenes with anilines
publisher Wiley-VCH
publishDate 2018-02-02
url http://hdl.handle.net/10261/183311
http://dx.doi.org/10.13039/501100003329
http://dx.doi.org/10.13039/501100000780
work_keys_str_mv AT monzondiegom mildbasepromotedarylationofheteroareneswithanilines
AT santostanausu mildbasepromotedarylationofheteroareneswithanilines
AT pinachocrisostomofernandor mildbasepromotedarylationofheteroareneswithanilines
AT martinvictors mildbasepromotedarylationofheteroareneswithanilines
AT carrillofumeroromen mildbasepromotedarylationofheteroareneswithanilines
_version_ 1777669784453775360

Similar Items