Mild-Base-Promoted Arylation of (Hetero)Arenes with Anilines
Transition metal-free radical arylation of heteroarenes is achieved at room temperature by simply adding aqueous sodium carbonate to a solution of the corresponding heteroarene and arenediazonium salt, which can even be formed in situ. Such an easy, inexpensive and mild methodology has been optimized and applied to the expeditious modification of interesting molecular cores like naphthylimide or bisthienylcyclopentenes.
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| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Published: |
Wiley-VCH
2018-02-02
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| Subjects: | Heterocycles, Dyes/pigments, Diazo compounds, C−C coupling, Radical reactions, |
| Online Access: | http://hdl.handle.net/10261/183311 http://dx.doi.org/10.13039/501100003329 http://dx.doi.org/10.13039/501100000780 |
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