Kinetics of the Thermal Degradation of granulated scrap tyres: a model-free analysis
[EN] Pyrolysis is a technology with a promising future in the recycling of scrap tyres. This paper determines the thermal decomposition behaviour and kinetics of granulated scrap tyres (GST) by examining the thermogravimetric/derivative thermogravimetric (TGA/DTG) data obtained during their pyrolysis in an inert atmosphere at different heating rates. The model-free methods of Friedman, Flynn-Wall-Ozawa and Coats-Redfern were used to determine the reaction kinetics from the DTG data. The apparent activation energy and pre-exponential factor for the degradation of GST were calculated. A comparison with the results obtained by other authors was made.
Main Authors: | , , , , |
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Format: | artículo biblioteca |
Language: | English |
Published: |
Kaunas University of Technology
2013
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Subjects: | Granulated scrap tyre, TGA/DTG, Kinetic, Pyrolysis, |
Online Access: | http://hdl.handle.net/10261/90515 |
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