Kinetics of the Thermal Degradation of granulated scrap tyres: a model-free analysis

[EN] Pyrolysis is a technology with a promising future in the recycling of scrap tyres. This paper determines the thermal decomposition behaviour and kinetics of granulated scrap tyres (GST) by examining the thermogravimetric/derivative thermogravimetric (TGA/DTG) data obtained during their pyrolysis in an inert atmosphere at different heating rates. The model-free methods of Friedman, Flynn-Wall-Ozawa and Coats-Redfern were used to determine the reaction kinetics from the DTG data. The apparent activation energy and pre-exponential factor for the degradation of GST were calculated. A comparison with the results obtained by other authors was made.

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Bibliographic Details
Main Authors: López Gómez, Félix Antonio, El Hadad, Amir A., Alguacil, Francisco José, Álvarez Centeno, Teresa, Lobato Ortega, Belén
Format: artículo biblioteca
Language:English
Published: Kaunas University of Technology 2013
Subjects:Granulated scrap tyre, TGA/DTG, Kinetic, Pyrolysis,
Online Access:http://hdl.handle.net/10261/90515
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