Synthesis of microporous polymers with exposed C60 surfaces by polyesterification of fullerenol
Microporous polymers with exposed C60 surfaces have been synthesized by a new pathway of crosslinking fullerenol and terephthaloyl chloride or 1,3,5-benzenetricarbonyl trichloride via esterification. The resulting polymers are insoluble solids containing a large ratio of C60 with hydroxy groups and possess micropores with high specific surface area up to 657 m2 g-1. The microporous polymers thus obtained exhibit enhanced hydrogen spillover, which is a unique property of the C60 surface.
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Language: | English |
| Published: |
Royal Society of Chemistry (UK)
2022-05-28
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| Online Access: | http://hdl.handle.net/10261/305206 https://api.elsevier.com/content/abstract/scopus_id/85131862928 |
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